Final Thoughts on Chemistry for 5-Methoxy-3,4-dihydro-2H-pyrrole

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Synthesis and mild retro Diels-Alder decomposition of 1,4-methanopyrrolo-, 1,4-methanopyrido- and 1,4-methanoazepino<2,1-b>quinazolinones

From norbornane- and norbornene-fused azetidinones 1a and 1b, 1,4-methanopyrrolo-, 1,4-methanopyrido- and 1,4-methanoazepino<2,1-b>quinazolinones 6a,b-9a,b were prepared by ring enlargement.Norbornene derivatives 6b-9b underwent retrodiene decomposition to give pyrrolo-, pyrido- and azepino<1,2-a>pyrimidinones 10-13, respectively.

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Reference£º
Pyrroline – Wikipedia,
1-Pyrroline | C4H7N – PubChem