Extended knowledge of 5-Methoxy-3,4-dihydro-2H-pyrrole

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Synthetic Route of 5264-35-7. In my other articles, you can also check out more blogs about 5264-35-7

Synthetic Route of 5264-35-7, A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 5264-35-7, Name is 5-Methoxy-3,4-dihydro-2H-pyrrole, molecular formula is C5H9NO. In a Article£¬once mentioned of 5264-35-7

PMR SPECTRA AND cis-trans ISOMERISM OF 2-METHYLENEPYRROLIDINE AND 2-METHYLENETETRAHYDROFURAN DERIVATIVES

A number of secondary enamines and cyclic enol ethers (2-methylenetetrahydrofuran derivatives) were synthesized by the reaction of O-methylbutyrolactim and 2,2-diethoxytetrahydrofuran, respectively, with compounds that have an active methylene link.The absence of reversible cis-trans isomerization was established in a study of the PMR spectra of these compounds.The configuration of the secondary enamines is determined by the possibility of the formation of a strong intramolecular hydrogen bond between the carbonyl-containing substituent and the NH group.In the case of the cyclic enol ethers it was shown that the energy barrier to cis-trans isomerization is greater than 25 kcal/mole and that, as a consequence of this, the geometrical isomers can be separated preparatively.

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Reference£º
Pyrroline – Wikipedia,
1-Pyrroline | C4H7N – PubChem