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Palladium-catalyzed asymmetric intermolecular cyclization
Domino cyclization: Alkylpalladium intermediates in an asymmetric Heck reaction were intercepted by a second alkene to give tricyclic products with high enantioselectivity (see scheme; Boc=tert-butoxycarbonyl). The method was applied to the asymmetric synthesis of a precursor of (-)-martinellic acid, a folk eye medicine in South America. Copyright
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Reference£º
Pyrroline – Wikipedia,
1-Pyrroline | C4H7N – PubChem