Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 110351-94-5, Name is (S)-4-Ethyl-4-hydroxy-7,8-dihydro-1H-pyrano[3,4-f]indolizine-3,6,10(4H)-trione, molecular formula is C13H13NO5. In an article, author is Pieta, Izabela S.,once mentioned of 110351-94-5, SDS of cas: 110351-94-5.
The Hallmarks of Copper Single Atom Catalysts in Direct Alcohol Fuel Cells and Electrochemical CO2 Fixation
Single-atom catalysts (SACs) are highly enviable to exploit the utmost utilization of metallic catalysts; their efficiency by utilizing nearly all atoms to often exhibit high catalytic performances. To architect the isolated single atom on an ideal solid support with strong coordination has remained a crucial trial. Herein, graphene functionalized with nitrile groups (cyanographene) as an ideal support to immobilize isolated copper atoms G(CN)-Cu with strong coordination is reported. The precisely designed mixed-valence single atom copper (G(CN)-Cu) catalysts deliver exceptional conversions for electrochemical methanol oxidation (MOR) and CO2 reduction (CO2RR) targeting a closed carbon cycle. An onset of MOR and CO2RR are obtained to be approximate to 0.4 V and approximate to-0.7 versus Ag/AgCl, respectively, with single active sites located in an unsaturated coordination environment, it being the most active Cu sites for both studied reactions. Moreover, G(CN)-Cu exhibited significantly lower resistivity and higher current density toward MOR and CO2RR than observed for reference catalysts.
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Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem