Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products, Computed Properties of C8H10NO6P, 54-47-7, Name is Pyridoxal phosphate, molecular formula is C8H10NO6P, belongs to pyrrolines compound. In a document, author is SIGMAN, MS, introduce the new discover.
THE FIRST IRON-MEDIATED CATALYTIC CARBON-NITROGEN BOND FORMATION – [4+1] CYCLOADDITION OF ALLENYL IMINES AND CARBON-MONOXIDE
Catalytic carbon-nitrogen bond formation was achieved by iron carbonyls in the [4 + 1] cycloaddition of allenyl imines with CO. The Fe(CO)(5) photochemically catalyzed reaction of allenyl imines and CO gives preparatively useful yields of 3-alkylidene-4-pyrrolin-2-ones. These reactions take place under mild conditions and only require fluorescent light! Good control of alkylidene bond stereochemistry is achieved when the terminal allene groups are tert-butyl and methyl. Experiments in the dark show that stoichiometric Fe-2(CO)(9) can mediate [4 + 1] assembly by a purely thermal reaction to give good yields of the pyrrolinone products. These new methods for the construction of 3-alkylidene-4-pyrrolin-2-ones are complimentary to existing procedures and allow for a greater variety of alkylidene substituents.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law. In my other articles, you can also check out more blogs about 54-47-7. Computed Properties of C8H10NO6P.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem