Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 3446-89-7, Name is 4-(Methylthio)benzaldehyde, molecular formula is C8H8OS. In an article, author is Skoch, Karel,once mentioned of 3446-89-7, Application In Synthesis of 4-(Methylthio)benzaldehyde.
Alkyne 1,1-Hydroboration to a Reactive Frustrated P/B-H Lewis Pair
The Mes(2)P-C equivalent to C-SiMe3 alkyne reacts with the borane H2B-Fmes by means of a rare 1,1-hydroboration reaction to give an unsaturated C-2-bridged frustrated P/B-H Lewis pair. Most of its reactions are determined by the presence of the B-H functionality at the FLP function and the activated connecting carbon-carbon double bond. It reduces carbon monoxide to the formyl stage. With nitriles it reacts in an extraordinary way: it undergoes a reaction sequence that eventually results in the formation of a P-substituted dihydro-1,2-azaborole derivative. Several similar examples were found. In one case a P-ylide was isolated that was related to an intermediate of the reaction sequence. It subsequently opened in an alternative way to give an alkenyl borane product.
Interested yet? Keep reading other articles of 3446-89-7, you can contact me at any time and look forward to more communication. Application In Synthesis of 4-(Methylthio)benzaldehyde.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem