Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 129946-88-9, Name is 5-(Trifluoromethyl)-5H-dibenzo[b,d]thiophen-5-ium trifluoromethanesulfonate, SMILES is [O-]S(=O)(=O)C(F)(F)F.FC(F)(F)[S+]1C2=CC=CC=C2C2=CC=CC=C12, in an article , author is Huo, Hao-Hua, once mentioned of 129946-88-9, Application In Synthesis of 5-(Trifluoromethyl)-5H-dibenzo[b,d]thiophen-5-ium trifluoromethanesulfonate.
Enantioselective Total Syntheses of (-)-FR901483 and (+)-8-epi-FR901483
The enantioselective total syntheses of the potent immunosuppressant FR901483 (1) and its 8-epimer (47) have been accomplished. Our approach features the use of building block 6 as the chiron, the application of the one-pot amide reductive bis-alkylation method to construct the chiral aza-quaternary center (dr = 9:1), regio- and diaster-eoselective intramolecular aldol reaction to build the bridged ring, and RCM to form the 3-pyrrolin-2-one ring.
But sometimes, even after several years of basic chemistry education, it is not easy to form a clear picture on how they govern reactivity! 129946-88-9, you can contact me at any time and look forward to more communication. Application In Synthesis of 5-(Trifluoromethyl)-5H-dibenzo[b,d]thiophen-5-ium trifluoromethanesulfonate.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem