Application of 291756-76-8, The transformation of simple hydrocarbons into more complex and valuable products via catalytic C–H bond functionalisation has revolutionised modern synthetic chemistry. 291756-76-8, Name is (Z)-N-[2-Chloro-3-(dimethylamino)allylidene]-N-methylmethanaminium Hexafluorophosphate, SMILES is C[N+](C)=C/C(Cl)=C/N(C)C.F[P-](F)(F)(F)(F)F, belongs to pyrrolines compound. In a article, author is Zhukovsky, Daniil, introduce new discover of the category.
Synthetic Exploration of alpha-Diazo gamma-Butyrolactams
DIazo transfer reaction onto -butyrolactams (activated by -ethyloxalylation) gave rare -diazo -butyrolactams. Decomposition of the latter by Rh-2(OAc)(4) in the presence of alcohols and water gave products of O-H insertion of the respective metal-cabene species. Silver triflate (1 mol-%) was found to convert the -butyrolactams investigated into 1,5-dihydro-2H-pyrrol-2-ones which represent versatile building blocks. Particular instability was noted for -diazo -butyrolactams bearing alkyl or o-substituted aryl substituents on the nitrogen atom. These were found to dimerize in solution or upon storage at room temperature to give fully conjugated bis-hydrazones along with the loss of a nitrogen molecule.
Application of 291756-76-8, Consequently, the presence of a catalyst will permit a system to reach equilibrium more quickly, but it has no effect on the position of the equilibrium as reflected in the value of its equilibrium constant.I hope my blog about 291756-76-8 is helpful to your research.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem