Chemistry is traditionally divided into organic and inorganic chemistry. The former is the study of compounds containing at least one carbon-hydrogen bonds. 163931-61-1, Name is Tetrabutylammonium difluorotriphenylsilicate(IV), molecular formula is C34H51F2NSi, belongs to pyrrolines compound, is a common compound. In a patnet, author is Muriel, Bastian, once mentioned the new application about 163931-61-1, Computed Properties of https://www.ambeed.com/products/163931-61-1.html.
Azide Radical Initiated Ring Opening of Cyclopropenes Leading to Alkenyl Nitriles and Polycyclic Aromatic Compounds
We report herein a radical-mediated amination of cyclopropenes. The transformation proceeds through a cleavage of the three-membered ring after the addition of an azide radical on the strained double bond and leads to tetrasubstituted alkenyl nitrile derivatives upon loss of N-2. With 1,2-diaryl substituted cyclopropenes, this methodology could be extended to a one-pot synthesis of highly functionalized polycyclic aromatic compounds (PACs). This transformation allows the synthesis of nitrile-substituted alkenes and aromatic compounds from rapidly accessed cyclopropenes using only commercially available reagents.
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Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem