Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Sanden, Sebastian A., once mentioned the application of 155899-66-4, Name is (3aR,4S,6R,6aS)-6-Amino-2,2-dimethyltetrahydro-3aH-cyclopenta[d][1,3]dioxol-4-ol, molecular formula is C8H15NO3, molecular weight is 173.2096, MDL number is MFCD20527303, category is pyrrolines. Now introduce a scientific discovery about this category, Category: pyrrolines.
Simultaneous synthesis of thioesters and iron-sulfur clusters in water: two universal components of energy metabolism
Thioesters are important intermediates in both synthetic organic and biosynthetic reaction pathways. Here we show that thioesters can be synthesized in an aqueous reaction between thioacetate and thiols. The reaction can be coupled to a second reaction between sulfide and either ferrous or ferric iron, which drives the reaction forward. We furthermore demonstrate that sulfide released during thioester formation can be used in the synthesis of peptide bound [Fe-S] clusters, which like thioesters, are ancient components of metabolism. Together our results reveal a primordial linkage between high-energy ester formation and redox chemistry.
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Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem