Chemical Research Letters, May 2021. The appropriate choice of redox mediator can avoid electrode passivation and overpotential, which strongly inhibit the efficient activation of substrates in electrolysis. COA of Formula: https://www.ambeed.com/products/110351-94-5.html,110351-94-5, Name is (S)-4-Ethyl-4-hydroxy-7,8-dihydro-1H-pyrano[3,4-f]indolizine-3,6,10(4H)-trione, SMILES is O=C1[C@](O)(CC)C(C=C23)=C(CO1)C(N3CCC2=O)=O, belongs to pyrrolines compound. In a document, author is Ahmad, Muhammad Siddique, introduce the new discover.
Cu-catalyzed cyanomethylation of imines and alpha,beta-alkenes with acetonitrile and its derivatives
We describe copper-catalyzed cyanomethylation of imines and alpha,beta-alkenes with a methylnitrile source and provide an efficient route to synthesize arylacrylonitriles and beta,gamma-unsaturated nitriles. This method tolerates aliphatic and aromatic alkenes substituted with a variety of functional groups such as F, Cl, Br, Me, OMe, tert-Bu, NO2, NH2 and CO2H with good to excellent yields (69-98%). These systems consist of inexpensive, simple copper catalyst and acetonitrile with its derivatives (alpha-bromo/alpha-iodo-acetonitrile) and are highly applicable in the industrial production of acrylonitriles.
Therefore, this conceptually novel strategy might open impressive avenues to establish green and sustainable chemistry platforms. 110351-94-5, you can contact me at any time and look forward to more communication. COA of Formula: https://www.ambeed.com/products/110351-94-5.html.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem