Chemical Research Letters, May 2021. The appropriate choice of redox mediator can avoid electrode passivation and overpotential, which strongly inhibit the efficient activation of substrates in electrolysis. Category: pyrrolines,29968-78-3, Name is 4-Nitrophenylethylamine hydrochloride, SMILES is NCCC1=CC=C([N+]([O-])=O)C=C1.[H]Cl, belongs to pyrrolines compound. In a document, author is Gore, Babasaheb Sopan, introduce the new discover.
De Novo Protocol for the Construction of Benzo[a]fluorenes via Nitrile/Alkene Activation
Unprecedented chemo- and regioselective synthesis of benzo[a]fluorenes and naphthamide-substituted benzo[a]fluorenes were constructed from the reaction of (E)-2-aroyl-3-(2-(arylalkynes/alkenes)aryl)acrylonitrile scaffolds under metal-free conditions via the activation of nitriles and alkenes, respectively. A tentative reaction mechanism was proposed for this homofunctionalization of nitriles. Control experiments showed that the reaction proceeds via selective nitrile or alkene protonation, depending upon the substrates. Additionally, we demonstrated an alternative expeditious route for the synthesis of disubstituted benzo[a]fluorenes in the presence of TfOH alone.
Therefore, this conceptually novel strategy might open impressive avenues to establish green and sustainable chemistry platforms. 29968-78-3, you can contact me at any time and look forward to more communication. Category: pyrrolines.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem