New research progress on 3317-61-1 in 2021. Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. 3317-61-1, Name is 5,5-Dimethyl-1-pyrroline N-oxide, molecular formula is C6H11NO, belongs to pyrrolines compound, is a common compound. In a patnet, author is Inguimbert, N, once mentioned the new application about 3317-61-1, COA of Formula: https://www.ambeed.com/products/3317-61-1.html.
Unexpected formation of new chiral 3-amino-5-alkyl-2,5-dihydro-1H-pyrrolin-2-ones from N-Boc-alpha-amino esters
We describe a one-pot process involving the DiBA1-H reduction of the ester moiety of N-protected α-amino esters, followed by Horner-Wadsworth-Emmons olefination in the presence of the trimethyl ester phosphonoglycinate carbanion allowing the formation of new chiral 3-amino-5-alkyl-2,5-dihydro-IH pyrrolin-2-one 5. The Z-enoate 4b, which is formed during this reaction, could be converted into the corresponding lactam 5b under UV irradiation with the presence of BuLi. © 2005 Elsevier Ltd. All rights reserved.
But sometimes, even after several years of basic chemistry education, it is not easy to form a clear picture on how they govern reactivity! 3317-61-1, you can contact me at any time and look forward to more communication. COA of Formula: https://www.ambeed.com/products/3317-61-1.html.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem