New Advances in Chemical Research, May 2021.Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. 636-41-9, Name is 2-Methyl-1H-pyrrole, molecular formula is C5H7N, belongs to pyrrolines compound, is a common compound. In a patnet, author is Ricko, Sebastijan, once mentioned the new application about 636-41-9, Safety of 2-Methyl-1H-pyrrole.
Organocatalyzed Deracemization of Delta(2)-Pyrrolin-4-ones
Racemic pyrrolin-4-ones, accessible from a-amino acids, undergo asymmetric stereoselective organocatalyzed 1,4-additions to trans-beta-nitrostyrenes (up to 98% ee; dr up to 97: 3). From a series of typical organocatalysts, the best performance was achieved using (+)-camphor-1,3-diamine-derived bifunctional organocatalysts. A broad substrate scope and some follow-up modifications have been demonstrated.
The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing quantitative kinetic, their interactions with reaction intermediates. Interested yet? Read on for other articles about 636-41-9. Safety of 2-Methyl-1H-pyrrole.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem