New Advances in Chemical Research, May 2021.Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. 54-47-7, Name is Pyridoxal phosphate, molecular formula is C8H10NO6P, belongs to pyrrolines compound, is a common compound. In a patnet, author is He, Xing, once mentioned the new application about 54-47-7, Computed Properties of https://www.ambeed.com/products/54-47-7.html.
Sodium as High-efficient Catalyst in Hydroboration of Unsaturated Compounds
The catalysts used to catalyze the hydroboration of nitriles or carbodiimides usually have some disadvantages such as complex structure, high cost, large pollution of environment and so on. It is an important development direction to use the main group metals instead of the transition metals to reduce the costs and realize green catalysis. In this paper, using NaH or NaOH as a catalyst, an efficient reaction of nitrile or carbodiimide with pinacol borane (HBPin) has been achieved. It was found that 3.5 mol% of NaH participated in the hydroboration reaction in a simple and effective method under slight solvent-free circumstances. In addition, intermolecular chemoselectivity hydroboration of nitrile and substrates with different functional groups was also investigated by employing three different catalysts. This reaction uses the inorganic alkali with simple structure, commercially available and low cost to synthesize organoborane compounds, which provides ideas for industrial development.
Therefore, this conceptually novel strategy might open impressive avenues to establish green and sustainable chemistry platforms. 54-47-7, you can contact me at any time and look forward to more communication. Computed Properties of https://www.ambeed.com/products/54-47-7.html.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem