Research speed reading in 2021. The transformation of simple hydrocarbons into more complex and valuable products via catalytic C–H bond functionalisation has revolutionised modern synthetic chemistry. 13472-00-9, Name is 4-(2-Aminoethyl)aniline, molecular formula is C8H12N2. In an article, author is Pal, M,once mentioned of 13472-00-9, Product Details of 13472-00-9.
A rapid and direct access to symmetrical/unsymmetrical 3,4-diarylmaleimides and pyrrolin-2-ones
1.8-Diazabicyclo[5.4.0]undec-7ene (DBU) facilitated the oxidative cyclization of phenacyl amide in the presence of atmospheric oxygen under environmentally friendly conditions. The reaction has been studied under various conditions and a plausible mechanism is proposed. This ‘green’ reaction proceeds via intramolecular ring closure of the amide followed by subsequent reaction with molecular oxygen where DBU played a crucial role. A variety of phenacyl amides were treated with DBU in acetonitrile under an oxygen atmosphere to dive the symmetrical/unsymmetrical 3.4-diarylsubstituted maleimides in good yields. Corresponding pyrrolin-2-ones however, were obtained in good to excellent yields when K2CO3 was used in place of DBU affording a practical synthesis of these compounds of potential biological interest. (C) 2004 Elsevier Ltd. All rights reserved.
The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing quantitative kinetic, their interactions with reaction intermediates. Interested yet? Read on for other articles about 13472-00-9. Product Details of 13472-00-9.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem