Research speed reading in 2021. The transformation of simple hydrocarbons into more complex and valuable products via catalytic C–H bond functionalisation has revolutionised modern synthetic chemistry. 494-19-9, Name is Iminodibenzyl, molecular formula is C14H13N. In an article, author is Roder, Anja,once mentioned of 494-19-9, Application In Synthesis of Iminodibenzyl.
Vacuum-Ultraviolet Absorption Spectrum of 3-Methoxyacrylonitrile
The high-resolution absorption spectrum of 3-methoxyacrylonitrile (3MAN) was measured between 5.27 and 12.59 eV using a synchrotron-based Fourier-transform spectrometer. It was related to an absolute absorption cross-section scale. Complementary calculations at the DFT-MRCl/aug-cc-pVTZ level of theory document the vertical transition energies and oscillator strengths toward the first 19 states of both the E and Z geometrical isomers of 3MAN. Comparisons with the experimental absorption spectrum reveal the similarities and differences between 3MAN, a bifunctional molecule, with acrylonitrile and methyl-vinylether, where only one functional group is present. As in acrylonitrile, several broad valence transitions were observed up to the ionization limit. They are likely associated with the extended pi-system induced by the nitrile group but might also involve sigma sigma* transitions close to the ionization limit. As in methylvinylether, Rydberg series converging to the ionization limit are absent. This is attributed to a difference in neutral and cationic geometry due to a 60 degrees rotation of the methyl group.
The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing quantitative kinetic, their interactions with reaction intermediates. Interested yet? Read on for other articles about 494-19-9. Application In Synthesis of Iminodibenzyl.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem