New Advances in Chemical Research, May 2021. Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages over direct electrolysis.556-50-3, Name is 2-(2-Aminoacetamido)acetic acid, molecular formula is C4H8N2O3, belongs to pyrrolines compound, is a common compound. In a patnet, author is Zhao, Xiaoyuan, once mentioned the new application about 556-50-3, Computed Properties of https://www.ambeed.com/products/556-50-3.html.
TBHP/TBAI-Mediated Oxidative Cascade Reaction Consisting of Dimerization, Cyclization, and 1,2-Aryl Migration: Metal-Free Synthesis of Pyrrolin-4-ones and Highly Substituted Pyrroles
Treatment of enamino esters with TBHP (t-butylhydroperoxide) and TBAI (t-butylammonium iodide) in HFIP (hexafluoroisopropanol) was found to afford a variety of substituted pyrrolin-4-one compounds. This metal-free oxidative cascade reaction consists of the key steps of coupling of two radical intermediates, an intramolecular ring closure, and an exclusive 1,2-aryl radical migration. Upon treatment with a base, the obtained pyrrolin-4-ones could be converted to the highly substituted pyrrole compounds.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law. In my other articles, you can also check out more blogs about 556-50-3. Computed Properties of https://www.ambeed.com/products/556-50-3.html.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem