Chemical Research Letters, May 2021. The appropriate choice of redox mediator can avoid electrode passivation and overpotential, which strongly inhibit the efficient activation of substrates in electrolysis. Application In Synthesis of Iminodibenzyl,494-19-9, Name is Iminodibenzyl, SMILES is C12=CC=CC=C1CCC3=CC=CC=C3N2, belongs to pyrrolines compound. In a document, author is Wang, Zikun, introduce the new discover.
Cu(II)-catalyzed cyclization of alpha-diazo-beta-oxoamides with amines leading to pyrrol-3(2H)-ones
A novel Cu(II)-catalyzed cyclization of alpha-diazo-beta-oxoamides with amines has been developed, constituting a straightforward method to construct pyrrol-3(2H)-one rings. The intramolecular hydrogen bonding effect in alpha-diazo-beta-oxoamides plays an essential role in this reaction. A plausible reaction mechanism involving divergent generation and subsequent [2 + 3] cyclization of ketene and alpha-diazoimine intermediates was proposed.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 494-19-9 is helpful to your research. Application In Synthesis of Iminodibenzyl.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem