New Advances in Chemical Research, May 2021. Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages over direct electrolysis.83411-71-6, Name is Bis(2,4,4-trimethylpentyl)phosphinic acid, molecular formula is C16H35O2P, belongs to pyrrolines compound, is a common compound. In a patnet, author is Demir, Ayhan S., once mentioned the new application about 83411-71-6, Formula: https://www.ambeed.com/products/83411-71-6.html.
New approaches to polysubstituted pyrroles and pyrrolinones from alpha-cyanomethyl-beta-ketoesters
In this present paper, we report the efficient, regioselective one-pot synthesis of 5-alkoxy and 5-alkylsulfanylpyrrole-3-carboxylates in high yields via the zinc perchlorate-catalyzed addition of alcohols and thiols to the nitrile carbon of alpha-cyanornethyl-beta-ketoesters followed by annulation. The addition-annulation process is undertaken in aqueous solution to give 4,5-dihydro-5-oxo-1H-pyrrole-beta-carboxylates (pyrrolinones) in good yields. These 4,5-dihydro-5-oxo-1H-pyrrole-3-carboxylates are also obtained by the hydrolysis of 5-alkoxypyrrole-3-carboxylates. (c) 2006 Elsevier Ltd. All rights reserved.
Therefore, this conceptually novel strategy might open impressive avenues to establish green and sustainable chemistry platforms. 83411-71-6, you can contact me at any time and look forward to more communication. Formula: https://www.ambeed.com/products/83411-71-6.html.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem