Application In Synthesis of Benzo[d][1,3]dioxole, New research progress on 274-09-9 in 2021.The appropriate choice of redox mediator can avoid electrode passivation and overpotential, which strongly inhibit the efficient activation of substrates in electrolysis. 274-09-9, Name is Benzo[d][1,3]dioxole, SMILES is C12=CC=CC=C1OCO2, belongs to pyrrolines compound. In a article, author is Demir, Ayhan S., introduce new discover of the category.
New approaches to polysubstituted pyrroles and pyrrolinones from alpha-cyanomethyl-beta-ketoesters
In this present paper, we report the efficient, regioselective one-pot synthesis of 5-alkoxy and 5-alkylsulfanylpyrrole-3-carboxylates in high yields via the zinc perchlorate-catalyzed addition of alcohols and thiols to the nitrile carbon of alpha-cyanornethyl-beta-ketoesters followed by annulation. The addition-annulation process is undertaken in aqueous solution to give 4,5-dihydro-5-oxo-1H-pyrrole-beta-carboxylates (pyrrolinones) in good yields. These 4,5-dihydro-5-oxo-1H-pyrrole-3-carboxylates are also obtained by the hydrolysis of 5-alkoxypyrrole-3-carboxylates. (c) 2006 Elsevier Ltd. All rights reserved.
By the way, if you are interested in learning more fun chemistry with your kids, get your hands into one chemistry set now, and start enjoying the best part of chemistry: experiments about 274-09-9. Application In Synthesis of Benzo[d][1,3]dioxole.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem