You could be based in a university, combining chemical research with teaching; working on developing and trialing new drugs; or helping to ensure national healthcare provision keeps pace with new discoveries. 163931-61-1, Name is Tetrabutylammonium difluorotriphenylsilicate(IV), molecular formula is C34H51F2NSi, belongs to pyrrolines compound, is a common compound. In a patnet, author is GIBSON, NJ, once mentioned the new application about 163931-61-1, Application In Synthesis of Tetrabutylammonium difluorotriphenylsilicate(IV).
ACYLATION OF ALDO 1-PYRROLINE 1-OXIDES (4,5-DIHYDRO-3H-PYRROLE 1-OXIDES) AND THE OXIDATION OF THE RESULTING 3-ACYLOXY-1-PYRROLINES (3-ACYLOXY-4,5-DIHYDRO-3H-PYRROLES)
5,5-Dimethyl-1-pyrroline 1-oxide (DMPO), when treated with NaH (1 mol) followed by ethyl chloroformate, benzoyl chloride, pivaloyl chloride or 2-bromoisobutyryl bromide gave the corresponding 3-acyloxy-1-pyrrolines. With NaH (2-4 mel) followed by benzoyl chloride or 2-bromoisobutyryl bromide, DMPO gave the corresponding 2-(3′-acyloxy-1′-pyrrolin-3′-yl)-3-acyloxypyrrolidines. Acylation of the 3-phenyl and 3-methyl DMPOs also gave the corresponding 3-acyloxy-1-pyrrolines. Oxidation of the 3-acyloxy-1-pyrrolines with m-CPBA gave the corresponding oxaziridines in good yield. These oxaziridines were resistant to ring opening by acid hydrolysis, photolysis and thermolysis.
Therefore, this conceptually novel strategy might open impressive avenues to establish green and sustainable chemistry platforms. 163931-61-1, you can contact me at any time and look forward to more communication. Application In Synthesis of Tetrabutylammonium difluorotriphenylsilicate(IV).
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem