The Shocking Revelation of 163931-61-1

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In chemical reaction engineering, simulations are useful for investigating and optimizing a particular reaction process or system. 163931-61-1, Name is Tetrabutylammonium difluorotriphenylsilicate(IV), molecular formula is C34H51F2NSi. In an article, author is Tolmacheva, I. A.,once mentioned of 163931-61-1, Application of 163931-61-1.

Synthesis and Transformation of Triterpenoids with a beta-Ketonitrile Fragment in Five-Membered Ring A

Triterpenoids with a beta-ketonitrile group in five-membered ring A were synthesized via intramolecular oxonitrile cyclization of C-3 methyl esters of 1-cyano-substituted 2,3-seco-triterpene acids. The intramolecular cyclization to form the triterpene ketonitriles and subsequent reduction of the oxo groups to give C-1 and C-3 substituents in the beta-orientation were confirmed to be stereoselective. Alkaline hydrolysis of the ketonitriles reduced the cyano groups to form the corresponding 3-oxo-2-nor-derivative while reduction and acylation of the beta-hydroxynitrile formed an alpha,beta-alkenenitrile fragment in the triterpenoid five-membered ring A.

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Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem