Reference of 54663-78-4, When developing chemical systems it’s of course important to gain a deep understanding of the chemical reaction process. 54663-78-4, Name is Tributyl(thiophen-2-yl)stannane, SMILES is CCCC[Sn](CCCC)(CCCC)C1=CC=CS1, belongs to pyrrolines compound. In a article, author is Palacios, Francisco, introduce new discover of the category.
Regioselective synthesis of pyrrolin-3-ones and 2,3,4,5-tetrahydro[1,3]-oxazines from N-vinylic amidines
Achiral and optically active N-vinylic amidines are obtained by simple addition of amidines to acetylenic esters. Thermal intramolecular cyclization of these Substrates containing a carboxylate group in position 3 gives pyrrolin-3-ones. The enaminone character of these compounds towards propargyl bromide, diethyl azodicarboxylate, diethyl acetylenedicarboxylate, ethyl propiolate and phenyl isocyanate is studied and functionalized pyrrolin-3-one derivatives are obtained. The reaction of the pyrrolinones prepared with diethyl ketomalonate leads to new 1,3-oxazine derivatives. (C) 2008 Elsevier Ltd. All rights reserved.
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Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem