As a society publisher, everything we do is to support the scientific community – so you can trust us to always act in your best interests, and get your work the international recognition that it deserves. 3446-89-7, Name is 4-(Methylthio)benzaldehyde, molecular formula is C8H8OS, belongs to pyrrolines compound, is a common compound. In a patnet, author is Tayu, Masanori, once mentioned the new application about 3446-89-7, Computed Properties of https://www.ambeed.com/products/3446-89-7.html.
A Catalytic Construction of Indoles via Formation of Ruthenium Vinylidene Species from N-Arylynamides
Treatment of ynamides with a catalytic amount of TpRuCl(PPh3)(2) resulted in the construction of indole scaffolds known as privileged structure motifs. This reaction involved a cascade of 1,2-rearrangement and cyclization carrying out C-C bond formation via a ruthenium vinylidene intermediate, as revealed by a deuterium-labeling experiments. Furthermore, the transformation of multi-functionalized ynamide, derived from a practical drug molecule, showed a high functional group tolerance of this reaction.
If you are hungry for even more, make sure to check my other article about 3446-89-7, Computed Properties of https://www.ambeed.com/products/3446-89-7.html.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem