Extended knowledge of tert-Butyl (4R-cis)-6-[(acetyloxy)methyl]-2,2-dimethyl-1,3-dioxane-4-acetate

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Academic researchers, R&D teams, teachers, students, policy makers and the media all rely on us to share knowledge that is reliable, accurate and cutting-edge.154026-95-6, Name is tert-Butyl (4R-cis)-6-[(acetyloxy)methyl]-2,2-dimethyl-1,3-dioxane-4-acetate, molecular formula is C15H26O6, belongs to pyrrolines compound, is a common compound. In a patnet, author is Woydziak, ZR, once mentioned the new application about 154026-95-6, Application of 154026-95-6.

Unusual tosyl transfer solvolysis reaction to 3-n-butyl-4-methyl-5,5-di-p-toluenesulfonyl-3-pyrrolin-2-one

The title compound (1) was isolated in 20-30% recovery following solvolysis of a mixture of 5-bromo-3-n-butyl-4-methyl-2-p-toluenesulfonylpyrrole (4b) and 5-bromo-4-n-butyl-3-methyl-2-p-toluenesulfonyl-pyrrole (4a) in trifluoroacetic acid and water, a reaction designed to produce 5-p-toluenesulfonyl-3-pyrrolin-2-ones, e.g., 5a and 5b.

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Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem