Chemical Research Letters, May 2021.Catalysts allow a reaction to proceed via a pathway that has a lower activation energy than the uncatalyzed reaction. In heterogeneous catalysis, catalysts provide a surface to bind in a process of adsorption. , Synthetic Route of 155899-66-4, Introducing a new discovery about 155899-66-4, Name is (3aR,4S,6R,6aS)-6-Amino-2,2-dimethyltetrahydro-3aH-cyclopenta[d][1,3]dioxol-4-ol, molecular formula is C8H15NO3, belongs to pyrrolines compound. In a document, author is Fusaka, T.
Synthesis and herbicidal activity of novel 3-alkoxycarbonyl-3-aryl-2, 3-dihydro-2-oxo-1H-pyrrole derivatives
In the course of efforts to find novel compounds with improved crop safety in transplanted rice by the modification of 1-[1-(3,5 -dichlorophenyl)-1-methylethyl]-4-methyl-3-phenyl-3-pyrrolin-2-one (1a), which was reported to have excellent herbicidal activity against paddy weeds, 2,3-dihydro-2-oxo-1H-pyrrole derivatives with a quaternary carbon atom having an alkoxycarbonyl group at the alpha-position of the cyclic amide were synthesized and examined. Among these compounds, methyl 1-[1-(3,5-dichlorophenyl)-1-methylethyl]-2,3-dihydro-4-methyl-2-oxo-3-phenyl-1H-pyrrole-3-carboxylate (2a) was not only active against Echinochloa oryzicola and Scirpus juncoides but also compatible with transplanted rice even in harsh conditions. On the bask of Preliminary experimental results. it was thought that 2a would generate the corresponding 2-oxo-3-pyrrolin (la) through the metabolic degradation of the methoxycarbonyl moiety. (C) Pesticide Science Society of Japan.
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Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem