You could be based in a university, combining chemical research with teaching; working on developing and trialing new drugs; or helping to ensure national healthcare provision keeps pace with new discoveries. 15875-13-5, Name is 3,3′,3”-(1,3,5-Triazinane-1,3,5-triyl)tris(N,N-dimethylpropan-1-amine), molecular formula is C18H42N6, belongs to pyrrolines compound, is a common compound. In a patnet, author is Trost, Barry M., once mentioned the new application about 15875-13-5, Recommanded Product: 15875-13-5.
Synthesis of Chiral, Densely Substituted Pyrrolidones via Phosphine-Catalyzed Cycloisomerization
Densely substituted chiral pyrrolidones are synthesized via phosphine-catalyzed cycloisomerization of enantioenriched beta-amino ynones, which are prepared in a single step using a highly enantioselective Zn-ProPhenol-catalyzed Mannich reaction. The exocyclic alkenes in the cyclization products provide versatile handles for further transformations and typically form with good E/Z selectivity. This cycloisomerization method can be performed in streamlined fashion, without purification of the intermediate Mannich adduct, and extends to anthranilic acid based scaffolds in addition to ProPhenol-derived Mannich adducts.
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Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem