The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing quantitative kinetic, spectroscopic, and theoretical assessments of solvent structures and their interactions with reaction intermediates. 155899-66-4, Name is (3aR,4S,6R,6aS)-6-Amino-2,2-dimethyltetrahydro-3aH-cyclopenta[d][1,3]dioxol-4-ol, molecular formula is C8H15NO3, belongs to pyrrolines compound, is a common compound. In a patnet, author is HOPMAN, JCP, once mentioned the new application about 155899-66-4, Formula: https://www.ambeed.com/products/155899-66-4.html.
CHIRALITY PRESERVATION IN PYRROLINONE IRON TETRACARBONYL COMPLEXES – A ROUTE TO ENANTIOPURE 5-SUBSTITUTED PYRROLINONES
The enantiopure iron complex 4 reacts under the influence of BF3 . OEt(2) with allylsilanes and enol acetates through a cationic intermediate in which the chirality of 4 is preserved, yielding enantiopure 5-substituted 3-pyrrolin-2-ones.
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Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem