We’ll be discussing some of the latest developments in chemical about CAS: 110351-94-5.110351-94-5, Name is (S)-4-Ethyl-4-hydroxy-7,8-dihydro-1H-pyrano[3,4-f]indolizine-3,6,10(4H)-trione, molecular formula is C13H13NO5, belongs to pyrrolines compound, is a common compound. In a patnet, author is Sattler, Lars E., once mentioned the new application about 110351-94-5, Recommanded Product: 110351-94-5.
Iodonium Cation-Pool Electrolysis for the Three-Component Synthesis of 1,3-Oxazoles
The synthesis of 1,3-oxazoles from symmetrical and unsymmetrical alkynes was realized by an iodonium cation-pool electrolysis of I-2 in acetonitrile with a well-defined water content. Mechanistic investigations suggest that the alkyne reacts with the acetonitrile-stabilized I+ ions, followed by a Ritter-type reaction of the solvent to a nitrilium ion, which is then attacked by water. The ring closure to the 1,3-oxazoles released molecular iodine, which was visible by the naked eye. Also, some unsymmetrical internal alkynes were tested and a regioselective formation of a single isomer was determined by two-dimensional NMR experiments.
The result showed that such a combination of chemo- and biocatalysis improved the catalytic yield more than two times compared with that of sole metal catalysis.I hope my blog about 110351-94-5 is helpful to your research. Recommanded Product: 110351-94-5.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem