Category: pyrrolines, New Advances in Chemical Research, May 2021. Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages over direct electrolysis. 1953-02-2, Name is Tiopronin, SMILES is O=C(O)CNC(C(S)C)=O, belongs to pyrrolines compound. In a article, author is Gein, V. L., introduce new discover of the category.
Reactions of 1,5-diaryl-4-heteroyl-3-hydroxy-3-pyrrolin-2-ones with arylamines and butylamine
1,5-Diaryl-4-[2-thienoyl(furanoyl)]-3-hydroxy-3-pyrrolin-2-ones reacted with aromatic amines to form arylamino-3-pyrrolin-2-ones. Reactions with butylamine occurred via intermediate salt formation followed by their transformation into 3-butylamino-3-pyrrolin-2-ones at heating.
The result showed that such a combination of chemo- and biocatalysis improved the catalytic yield more than two times compared with that of sole metal catalysis.I hope my blog about 1953-02-2 is helpful to your research. Category: pyrrolines.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem