Synthetic Route of 13950-21-5, Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps.In a article, 13950-21-5, molcular formula is C5H7NO, introducing its new discovery.
Cycloaddition of nitrile oxides to cyclic and acyclic alpha,beta-unsaturated amides. Frontier orbital interactions and an unexpected steric drift determine regiochemistry
The regiochemistry of the cycloadditions of nitrile oxides to alpha,beta- unsaturated amides is determined by frontier orbital interactions and by a regiochemical drift due to steric effects. Cycloadditions to alpha,beta- unsaturated lactames afford mainly 4-carboxamido-isoxazolines with high regioselectivity. In cycloadditions to acyclic alpha,beta-unsaturated amides the regioselectivity relaxes and finally reverses in the case of N,N- disubstituted derivatives, because of the increasing steric congestion at the amine nitrogen.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 13950-21-5 is helpful to your research. Synthetic Route of 13950-21-5
Reference£º
Pyrroline – Wikipedia,
1-Pyrroline | C4H7N – PubChem