Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Sattler, Lars E., once mentioned the application of 5306-85-4, Name is (3R,3aR,6S,6aR)-3,6-Dimethoxyhexahydrofuro[3,2-b]furan, molecular formula is C8H14O4, molecular weight is 174.1944, MDL number is MFCD00064828, category is pyrrolines. Now introduce a scientific discovery about this category, Recommanded Product: 5306-85-4.
Iodonium Cation-Pool Electrolysis for the Three-Component Synthesis of 1,3-Oxazoles
The synthesis of 1,3-oxazoles from symmetrical and unsymmetrical alkynes was realized by an iodonium cation-pool electrolysis of I-2 in acetonitrile with a well-defined water content. Mechanistic investigations suggest that the alkyne reacts with the acetonitrile-stabilized I+ ions, followed by a Ritter-type reaction of the solvent to a nitrilium ion, which is then attacked by water. The ring closure to the 1,3-oxazoles released molecular iodine, which was visible by the naked eye. Also, some unsymmetrical internal alkynes were tested and a regioselective formation of a single isomer was determined by two-dimensional NMR experiments.
Do you like my blog? If you like, you can also browse other articles about this kind. Thanks for taking the time to read the blog about 5306-85-4, Recommanded Product: 5306-85-4.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem