Chemical Research Letters, May 2021. The appropriate choice of redox mediator can avoid electrode passivation and overpotential, which strongly inhibit the efficient activation of substrates in electrolysis. Product Details of 112275-50-0,112275-50-0, Name is tert-Butyl 1,4-diazepane-1-carboxylate, SMILES is O=C(N1CCNCCC1)OC(C)(C)C, belongs to pyrrolines compound. In a document, author is Martin-Lopez, MJ, introduce the new discover.
Synthesis of azaspiro[4.5]decane systems by oxidative cyclization of olefinic precursors
The synthesis of 6-benzyloxycarbonyl-1-oxa-6-azaspiro[4,5]decan-2-one (17) and 6-benzyloxycarbonyl-1,6-diazaspiro[4.5]decan-2-one (18) from the D,L-pipecolic acid derivative 10, is described. The synthesis of (+/-)-6-benzyl-3-methyl-1,6-diazaspiro[4.5]dec-3-ene-2,7-dione (29), the spiro structural unit of (+/-)-pandamarine (8) has been achieved by oxidative cylization of the (Z) and (E) isomers of 5-(N-benzyl-4-carboxamidobutylidene)-3-methyl-3-pyrrolin-2-one (25) and (26). The stereoselectivity obtained in the intramolecular cyclization process has also been discussed. (C) 1998 Elsevier Science Ltd. All rights reserved.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions. you can also check out more blogs about 112275-50-0. Product Details of 112275-50-0.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem