Related Products of 1119-34-2, New research progress on 1119-34-2 in 2021.The appropriate choice of redox mediator can avoid electrode passivation and overpotential, which strongly inhibit the efficient activation of substrates in electrolysis. 1119-34-2, Name is Argininine monohydrochloride, SMILES is O=C(O)[C@@H](N)CCCNC(N)=N.[H]Cl, belongs to pyrrolines compound. In a article, author is Yu, Shuling, introduce new discover of the category.
Palladium-catalyzed tandem reaction of epoxynitriles with arylboronic acids in aqueous medium: divergent synthesis of furans and pyrroles
The efficient selective synthesis of furans and pyrroles has been realized by means of a palladium-catalyzed tandem addition/ring-opening/cyclization reaction of 2-(3-aryloxiran-2-yl)acetonitriles with arylboronic acids in aqueous medium for the first time. The chemoselectivity of this transformation can be predominantly governed by the steric effects of arylboronic acids: the reactions of 2-(3-aryloxiran-2-yl)acetonitriles with the less sterically hindered arylboronic acids provided furans as the sole products, while those of the sterically bulky arylboronic acids delivered pyrroles selectively. The O-18-labelled experiments revealed that the oxygen atom of furans is derived from water, and a plausible mechanism for this selective synthesis of furans and pyrroles was proposed.
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Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem