New Advances in Chemical Research, May 2021.Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. 56353-15-2, Name is (S)-2-(3-Acetamidopropanamido)-3-(1H-imidazol-4-yl)propanoic acid, molecular formula is C11H16N4O4, belongs to pyrrolines compound, is a common compound. In a patnet, author is Hunter, R, once mentioned the new application about 56353-15-2, Recommanded Product: (S)-2-(3-Acetamidopropanamido)-3-(1H-imidazol-4-yl)propanoic acid.
Synthesis of the tricyclic core of the marine alkaloid Lepadiformine
A stereoselective synthesis of the tricyclic core in racemic form of the marine alkaloid Lepadiformine is described from 4-methoxy-3-pyrrolin-2-one (methyl tetramate). Key steps involve 5,5-dialkylation of the tetramate, metathesis closure to an A/C 1-azaspirocycle and stereoselective hydrogenation for the trans A/B 1-azadecalin system.
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Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem