Chemical Research Letters, May 2021. As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world., Computed Properties of https://www.ambeed.com/products/112275-50-0.html, Introducing a new discovery about 112275-50-0, Name is tert-Butyl 1,4-diazepane-1-carboxylate, molecular formula is C10H20N2O2, belongs to pyrrolines compound. In a document, author is Zhang, Jing.
Acceptorless dehydrogenative coupling with Ru-based catalysts for the synthesis of N-heteroaromatic compounds
Ru-Catalyzed acceptorless dehydrogenative coupling (ADC) and auto-transfer-hydrogenative (ATH) reactions are effective, versatile transformations for the constructions of N-heteroaromatic compounds from alcohols. Water and hydrogen are the by-products and the starting alcohols are less toxic, more readily available and more easily handled than their halogenated counterparts. A variety of homogeneous ruthenium catalysts, alcohols and partner-substrates such as amines, ammonia, amidines and nitriles, have been used to build N-heteroaromatic compounds in one-pot, multi-step syntheses. This review details recently reported Ru catalysts employed for these reactions, describing the scope of each methodology, proposed reaction mechanisms, regioselectivity of coupling and applications in synthesis.
Therefore, this conceptually novel strategy might open impressive avenues to establish green and sustainable chemistry platforms. 112275-50-0, you can contact me at any time and look forward to more communication. Computed Properties of https://www.ambeed.com/products/112275-50-0.html.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem