New Advances in Chemical Research, May 2021. Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages over direct electrolysis.163931-61-1, Name is Tetrabutylammonium difluorotriphenylsilicate(IV), molecular formula is C34H51F2NSi, belongs to pyrrolines compound, is a common compound. In a patnet, author is Huang, Jiuzhong, once mentioned the new application about 163931-61-1, Safety of Tetrabutylammonium difluorotriphenylsilicate(IV).
Palladium-Catalyzed Intermolecular Oxidative Cyclization of Allyltosylamides with AcOH: Assembly of 3-Pyrrolin-2-ones
The first example of Pd-catalyzed oxidative cyclization of allyltosylamides with acetic acid is reported. This transformation involved C-N/C-C bond formation and provided 3-pyrrolin-2-ones in a one-pot manner with easy-operation, excellent atom economy and good yields. Mechanistic studies indicate that the reaction proceeds through intermolecular aminopalladation, migratory insertion, reinsertion and beta-hydride elimination processes.
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Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem