Reference of 13472-00-9, Chemistry involves the study of all things chemical – chemical processes, chemical compositions and chemical manipulation – in order to better understand the way in which materials are structured, how they change and how they react in certain situations. 13472-00-9, Name is 4-(2-Aminoethyl)aniline, SMILES is NCCC1=CC=C(N)C=C1, belongs to pyrrolines compound. In a article, author is Mun, JiYoung, introduce new discover of the category.
N-benzyl-5-hydroxy-3-pyrrolidin-2-one by hydrogen peroxide oxidation of n-benzyl-3-phenylseleno-2-pyrrolidinone
Using the known peroxide oxidation of N-benzyl-3-phenylseleno-2-pyrrolidinone with 30% hydrogen peroxide at – 5 degrees C after 3.5 h, we prepared the expected N-benzyl-3-pyrrolin-2-one. However, reaction with 30% hydrogen peroxide for 12 h (-5 degrees C -> ambient) gave the unexpected product N-benzyl-5-hydroxy-3-pyrrolidin2-one in 84% isolated yield. This procedure is a new synthetic route to N-benzyl-5hydroxy-3-pyrrolidin-2-one.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions. you can also check out more blogs about 13472-00-9. Reference of 13472-00-9.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem