Application of 129946-88-9, New research progress on 129946-88-9 in 2021.The appropriate choice of redox mediator can avoid electrode passivation and overpotential, which strongly inhibit the efficient activation of substrates in electrolysis. 129946-88-9, Name is 5-(Trifluoromethyl)-5H-dibenzo[b,d]thiophen-5-ium trifluoromethanesulfonate, SMILES is [O-]S(=O)(=O)C(F)(F)F.FC(F)(F)[S+]1C2=CC=CC=C2C2=CC=CC=C12, belongs to pyrrolines compound. In a article, author is Reginato, G, introduce new discover of the category.
Stannylcupration of chiral gamma-amino acetylenic esters: stereocontrolled synthesis of 3-tributylstannyl gamma-amino (E)-alkenoates as precursors of 4-stannylated pyrrolinones.
4-Tributylstannyl-5-substituted-pylrolin-2-ones are prepared through the addition of tributylstannyl cyano cuprate to enantiomerically enriched N-protected gamma-amino acetylenic esters. The regio- and stereoselectivity of the addition is discussed as a function of the substrates and of the reaction conditions. Cyclization of the (E)-isomers to the corresponding 4-stannylated pyrrolin-2-ones is reported, (C) 1998 Elsevier Science Ltd. All rights reserved.
Application of 129946-88-9, Consequently, the presence of a catalyst will permit a system to reach equilibrium more quickly, but it has no effect on the position of the equilibrium as reflected in the value of its equilibrium constant.I hope my blog about 129946-88-9 is helpful to your research.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem