Recommanded Product: Tetrabutylammonium difluorotriphenylsilicate(IV), New discoveries in chemical research and development in 2021. In classical electrochemical theory, both the electron transfer rate and the adsorption of reactants at the electrode control the electrochemical reaction. 163931-61-1, Name is Tetrabutylammonium difluorotriphenylsilicate(IV), SMILES is CCCC[N+](CCCC)(CCCC)CCCC.F[Si-](C1=CC=CC=C1)(C2=CC=CC=C2)(F)C3=CC=CC=C3, belongs to pyrrolines compound. In a article, author is Li, Xuan, introduce new discover of the category.
Copper- and DMF-mediated switchable oxidative C-H cyanation and formylation of imidazo[1,2-a]pyridines using ammonium iodide
The cyanation and formylation of imidazo[1,2-a]pyridines were developed under copper-mediated oxidative conditions using ammonium iodide and DMF as a nontoxic combined cyano-group source and DMF as a formylation reagent. Mechanistic studies indicate that the cyanation of imidazo[1,2-a]pyridines proceeds through a two-step sequence: initial iodination and then cyanation. The cyanation has a broad substrate scope and high functional group tolerance, and can be safely conducted on a gram scale. A novel copper-mediated formylation using the widely available DMF as the formylation reagent and environmentally friendly molecular oxygen as the oxidant has also been developed. This protocol also provided a convenient approach for the synthesis of clinically used saripidem.
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Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem