In heterogeneous catalysis, the catalyst is in a different phase from the reactants. Computed Properties of C9H15NO2, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 73286-71-2, name is N-Boc-2-pyrroline. In an article£¬Which mentioned a new discovery about 73286-71-2
RhII-Catalyzed beta-C(sp2)?H Alkylation of Enol Ethers, Enamides and Enecarbamates with alpha-Diazo Dicarbonyl Compounds
A RhII-catalyzed method for intermolecular alkylation of the beta-C(sp2)?H bond of enol ethers, enamides, and enecarbamates with alpha-diazo-1,3-dicarbonyl compounds is reported. The products are formed in up to 99 % yield and can be readily derivatized under a variety of conditions. By utilizing a combination of experimental and computational studies, the presumptive addition?elimination reaction mechanism was investigated and found to proceed under thermodynamic control at higher temperature. The acquired fundamental knowledge was translated into a strategic reaction design and yielded the first example of the beta-C?H functionalizations of acyclic enol ethers using alpha-diazo-1,3-dicarbonyl compounds.
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Reference£º
Pyrroline – Wikipedia,
1-Pyrroline | C4H7N – PubChem