Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Electric Literature of 1122-10-7. In my other articles, you can also check out more blogs about 1122-10-7
Electric Literature of 1122-10-7, A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 1122-10-7, Name is 3,4-Dibromo-1H-pyrrole-2,5-dione, molecular formula is C4HBr2NO2. In a Article£¬once mentioned of 1122-10-7
Macrolactones built from the bis-3,4(indol-1-yl)maleimide scaffold
15, 16, and 17-Membered lactones based on the bis-3,4(indol-1-yl)maleimide framework were obtained using intramolecular esterification reaction starting from 3-(1-omega-carboxyalkyl-2,3-dihydroindol-1-yl)-4-(1-omega-hydroxyalkyl- 2,3-dihydroindol-1-yl)-maleimides. 3,4-Dibromo-maleimide, omega-(2,3- dihydroindol-3-yl)alkanoic acids, and omega-(2,3-dihydroindol-3-yl)alkanoles were used as starting compounds. Substitution of Br for the substituted indolines followed by the intramolecular cyclization of O-silylated hydroxyl acids derivatives led to macrolactones that incorporated 4-(dihydroindol-1-yl)- 3-(indol-1-yl)maleimide moieties. Indoline nuclei in these compounds were dehydrogenated by DDQ in refluxing toluene to give 15, 16 or 17-membered lactones 3-[(omega-3-carboxyalkylindol-1-yl)-4-(omega-hydroxyalkylindol-1- yl)maleimides. Quantum chemical calculations showed that the formation of macrolactones of smaller size (13-membered) corresponds to the higher Gibbs energy DeltaG# and correlates with the absence of the target reaction product.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Electric Literature of 1122-10-7. In my other articles, you can also check out more blogs about 1122-10-7
Reference£º
Pyrroline – Wikipedia,
1-Pyrroline | C4H7N – PubChem